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Arnold M. Guloy
Associate Professor

Honors and Awards
NSF CAREER Award UH Research Excellence Award

Research Emphasis
Solid State and Main Group Chemistry


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Materials Research Interests Materials Publications

Zintl Phases and Polar Intermetallics.
The underdeveloped chemistry of intermetallics and their unpredictable phase stabilities offer serious challenges and immense opportunities to solid state chemists. Our synthetic explorations illustrates a virtual gold mine of remarkable stoichiometries, unprecedented structures, and novel chemical bonding exhibited by polar intermetallics and Zintl phases. These include low-dimensional intermetallics and novel intermetallic p-systems.

Hybrid Materials and Nanostructures.
We synthesize new low-dimensional hybrid organic-inorganic materials that exhibit desirable optical and electronic properties. We also develop unique strategies to generate high quality and well-defined nanoscale clusters, chains and thin films. These studies will improve our understanding of the basic and fundamental chemical issues such as organic-inorganic interactions, molecular orientation, structure-property modulation that will allow for the design and fabrication of new functional materials with tunable physical and chemical properties.

Ba2NiSi3: A One-Dimensional Solid-State Metallocene Analog, Journal of the American Chemical Society, 2000, 122, 10478-10479.

An Unprecedented [Ge9]2- Polymer: A Link Between Molecular Zintl Clusters and Solid-state Phases, Angewandte Chemie International Edition, 2000, 39, 338-340.

Synthesis and Crystal Structure of Ae2LiInGe2 (Ae = Ca, Sr): New Zintl Phases with a Layered Silicate-like Network, Inorganic Chemistry, 2001, 40, 4472-4477.

A New Luminescent Organic-Inorganic Hybrid Compound with Large Optical Nonlinearity, Advanced Materials, 2001, 13, 833 – 837.

A Methylviologen Lead(II) Iodide: Novel [PbI3]- Chains with Mixed Octahedral and Trigonal Prismatic Coordination, Journal of the American Chemical Society 1999, 121, 452-453.

Conducting Layered Organic-Inorganic Halides Containing <110>-oriented Perovskite Sheets, Science, 1995, 267, 1473-1476.