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We
investigate the design and synthesis
of organic and polymer materials
capable of controlled-assembly or
self-organization to form ultrathin
films. This includes incorporating
functional groups in amphiphiles,
polymerization on surfaces, and
preparation of p-electron conjugated
oligomers and polymers. These materials
are often: photochromic, electrically
conducting, photo-luminescent, electro-luminescent,
and nonlinear optically active.
Electropolymerization is utilized
to synthesize conjugated polymer
ultrathin films in-situ. We are
also involved in investigating nanoparticles,
nanostructured surfaces, and nanocomposite
materials primarily with an organic
or polymer component.
In
the area of biotechnology, there
is interest in the preparation and
application of these materials for
bioadhesion, biosensors, and drug
delivery. In summary, the projects
and approaches are multidisciplinary,
combining elements of organic and
polymer synthesis, physical methods,
and even engineering.
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Simultaneous
Surface Plasmon Optical and
Electrochemical Investigation
of Layer-by-Layer Self-Assembled
Conducting Ultrathin Polymer
Films" Langmuir
2002; 18(12); 4648-4652.
“Living
Anionic Surface-Initiated Polymerization
(LASIP) of a Polymer on Silica
Nanoparticles”,
Langmuir 2002; 18(8); 3324-3331.
“In-Plane
Photoalignment of Liquid Crystals
by Azobenzene-Polyelectrolyte
Layer-by-Layer Ultrathin Films,”
Langmuir; 2002; 18(11); 4532-4535.
“In
Situ Investigations of the Electrodeposition
and Electrochromic Properties
of Poly(3,4-ethylenedioxythiophene)
Ultrathin Films by Electrochemical-Surface
Plasmon Spectroscopy,”
Langmuir; 2002; 18(9); 3555-3560.
“Evanescent
Waveguide and Photochemical
Characterization of Azobenzene
Functionalized Dendrimer Ultrathin
Films" - Langmuir
2002 18(5),1688-1694. |